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Phase I began with "Iron Man" starring Robert Downey Jr. Iron Man
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A timeline of Phase I of the Marvel Cinematic Universe
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The second "Iron Man" film was released in 2010. IM2 Trailer
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"Thor" starring Chris Hemsworth and Tom Hiddleston, was the third film in the MCU. Thor Plot
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"Captain America" starring Chris Evans as the America's First Avenger, premiered in Hollywood in June of 2011 before its' nationwide release.
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"The Avengers" grossed over $1.5 billion dollars worldwide and ended Phase I of the MCU.