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Humans aquired there first ally on the battlefield when they had horses.
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When we used the first bow and arrow it was mainly used for hunting and then we saw how powerful and useful they were so we weaponized them and then turned them into our war weapons.
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A Trebuchet was an ancient war engine that developed from the sling shot.
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Gun Powder was inventd in the late 9th Century.
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The first Hand Cannon was developed in the 9th Century.