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Pizarro had joined an expedition and they had gone near Inca borders. He had always heard of rumors of gold along there but the men and Pizarro on this expedition had turned around before they had actually reached the Inca themselves.
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Francisco Pizarro made first contact with the Inca empire
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Vincente wanted catholicism to be accepted but the emperor ended up feeling insulted by this which then lead to Pizarro ordering an attack. They ended up capturing Atahulpa.
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Pizarro killed their emperor for breaking a deal that they had so he executed him.